That not how it tends to come out over the longer term.Good players outperform XG, it’s only natural really.... consider it... Whether Kane or Sissoko get a chance from 10 yards out, centre of the goal, only the keeper to beat from a through ball delivered from a central area just outside the box. Kane scores his chance, Sissoko misses. XG is 0.5. Of corse the true numbers for those players are actually 0.8 and 0.1.
What the numbers show is that the better players tend to be in a position for and take shots from higher xG positions.